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E5.03 - The Construction of Tandem Dye-Sensitized Solar Cells from Chemically-Derived Nanoporous Photoelectrodes 
Date/Time:
April 8, 2015   11:00am - 11:15am
 
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A tandem dye-sensitized solar cell (tandem-DSSC) was synthesized on the basis of thin-film semiconductor electrodes. The nanoporous p-type NiO films were successfully obtained by simultaneous deposition of Al and Ni, followed by selective etching of Al and oxidation. Likewise, the n-type photoanode was made where Ag was etched in nitric acid after the initial formation of Ag/TiO2 nanocomposites. Such dye-sensitized photoelectrodes were combined to construct a tandem solar cell which exhibited an enhanced open-circuit voltage. Also, the tandem devices were subjected to various light fluxes to correlate the experimental cell parameters (open-circuit voltage, short-circuit current, fill factor, recombination shunt resistance, etc.) with the ideal one-diode model. Interestingly, impedance spectra of the tandem cell was well matched with the parameters from each of the n-type or p-type DSSC, indicative of successfully-designed tandem structure. [1] C. Nahm, H. Choi, J. Kim, S. Byun, S. Kang, T. Hwang, H. H. Park, J. Ko, and B. Park, Nanotechnology 24, 365604 (2013). [2] A. Nattestad, A. J. Mozer, M. K. R. Fischer, Y.-B. Cheng, A. Mishra, P. B�uerle, and U. Bach, Nat. Mater. 9, 31 (2010). Corresponding Author: Byungwoo Park: byungwoo@snu.ac.kr
 


 
 
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