Keyword Suggestions

UU1.07 - III-V Compound Semiconductor Nanowires 
April 22, 2014   10:15am - 10:45am

With the continuous miniaturization of semiconductor materials and devices, high aspect ratio semiconductor nanostructures, such as nanowires, have become a primary candidate for next generation electronic and optoelectronic devices. As- and P-based III-V compound semiconductor nanowires are of particular interest for optoelectronic devices due to their high carrier mobility and optical emission efficiency compared to indirect-bandgap group IV materials. In this report, various III-V semiconductor nanowires, including GaAs, InP, InAs nanowires and related nanowire heterostructures, were grown epitaxially on GaAs, InP, InAs (111)B or Si (111) substrates by metalorganic chemical vapor deposition (MOCVD) using Au nanoparticles as catalyst. Some challenging issues related to the growth of III-V semiconductor nanowires by MOCVD and their implications on optical properties will be reviewed. In addition, some prototype nanowire devices such as GaAs/AlGaAs nanowire lasers and solar cell devices have been demonstrated.Firstly, GaAs nanowires with high optical and crystal quality were demonstrated by choosing an appropriate V/III ratio together with growth temperature. By passivating the GaAs nanowires with a AlGaAs shell, 1.9 ns of minority carrier lifetime has been obtained at room temperature. Precise control of crystal structure either in zincblende (ZB) crystal or wurtzite (WZ) crystal phase or mixed phases was also demonstrated in various III-V semiconductor nanowires. This unique phenomenon in nanowires which can not be realized in their bulk counterpart opens new possibilities for engineering nanowire devices.Prototype nanowire solar cell devices were fabricated by planarizing the GaAs/AlGaAs/GaAs nanowire structures. The devices exhibit a spectrally broad photo-response and the conversion efficiency can be over 4%. Modeling of Nanowire lasers has also been carried out by calculating the threshold gain for nanowire guided modes as a function of nanowire diameter and length. Gain spectrum for GaAs nanowires as a function of injected carrier density was modeled using microscopic gain theory. Based on these calculations, we have optimized the structure design for nanowire laser devices. The prototype GaAs/AlGaAs/GaAs nanowire laser structures were grown and optically pumped laser operation was demonstrated at room temperature.

Average Rating: (No Ratings)
  Was great, surpassed expectations, and I would recommend this
  Was good, met expectations, and I would recommend this
  Was okay, met most expectations
  Was okay but did not meet expectations
  Was bad and I would not recommend this

Keynote Address
Panel Discussion - Different Approaches to Commercializing Materials Research
Business Challenges to Starting a Materials-Based Company
Fred Kavli Distinguished Lectureship in Nanoscience
Application of In-situ X-ray Absorption, Emission and Powder Diffraction Studies in Nanomaterials Research - From the Design of an In-situ Experiment to Data Analysis